• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A method of manufacturing a watch piece (40) whose variation of hardness and metallic luster is low is presented. The method of manufacture comprises a heat treatment step, in which, by applying heat treatment to a watch piece (40), a plurality of crystals (41, 42 and 43) of titanium or the like, a step of shaping (shape processing), in which the watch part (40) is shaped, an etching step, in which, by subjecting the titanium or the like to etching, a mirror finish is produced on the outer surfaces (41s, 42s and 43s) crystals (41, 42 and 43), and the normal directions (41v, 42v and 43v) are made to these surfaces (41s, 42s and 43s) different from each other, and an anodizing step, in which anodizing is carried out on the surface (40s) of the watch piece (40).
    公开号:CH704289B1
    申请号:CH01988/11
    申请日:2011-12-16
    公开日:2016-06-30
    发明作者:Murazumi Takuya；Araki Akiko；Niwa Takashi；Kishi Matsuo
    申请人:Seiko Instr Inc；
    IPC主号:
    专利说明:

    Background of the invention
    1. Field of the invention
    The present invention relates to a method of manufacturing a watch part and a watch part.
    2. Description of the state of the art
    As the material of a watch piece, titanium or a titanium alloy (hereinafter referred to as "titanium or similar"), which is lightweight material, is widely used. By anodizing process with respect to the watch piece formed by titanium or the like after forming process (shape processing), corrosion resistance can be achieved. In addition, by adjusting the state of the anodizing process, different hues can be obtained. In general, it is difficult to obtain a metallic luster in the anodizing process over titanium or the like. As a result, there is the problem that the watch piece lacks a high-end appearance.
    In JP-A-11-100 627 (patent reference 1), the following technology is described as a method of manufacturing a titanium product or a titanium alloy product. That is, the titanium or titanium alloy material is heated in a vacuum or an inert gas at a temperature of 900 ° C to 1500 ° C and crystalline grains, including twin crystals, of 100 μm or more are precipitated on a part of the entire surface or the end. In the titanium or titanium alloy product made according to the above method, a crystal surface is aligned in slightly different directions with respect to the normal direction of the metal surface and it is considered that the crystalline surface shines brightly. according to the angle of vision.
    However, in order to obtain a sufficient metallic luster in the patent reference 1, it is necessary to guarantee / provide a light reflection zone of the crystalline surface by making the crystalline grains grow to several millimeters or more in reality. When the invention of the patent reference 1 is applied to a watch piece which is a tiny piece, and the crystalline grains are made larger than the watch piece, it is likely that the watch piece is formed for each grain (consists of a single crystal). In general, since the hardness of a polycrystalline titanium material or the like is different for each crystal, when the watch piece is formed for each crystal, the hardness of the watch piece eventually varies.
    Summary of the invention
    According to one aspect of the present invention, there is provided a method of manufacturing a watch part and a watch part whose variation in hardness and metal luster is low.
    According to the present invention, a method of manufacturing a watch piece according to one of claims 1 to 4 appended comprises, in addition to a shaping step in which the watch piece is shaped, a step of heat treatment in which, by applying a heat treatment to the polycrystalline material, a plurality of crystals included in the polycrystalline material is made to swell, and an etching step in which, by subjecting the polycrystalline material to etching, a mirror finish is produced on the external surfaces of the crystals, and the directions normal to these surfaces are rendered different from each other.
    According to the invention, since the crystals are made larger by the heat treatment step, a metal luster is produced on the surface of the watch piece. In addition, in the case where the metallic luster is insufficient due to the fact that the action of making the crystals grow (the increase in the particle size of the crystals) is limited to suppress a variation of the hardness of the watch piece, the surfaces of each crystal obtain a mirror finish during the etching step, and the directions normal to the surfaces of each crystal are different from each other. As a result, a shiny metallic luster may be produced on the surface of the watch piece.
    In addition, it is preferred to enlarge a crystal grain diameter to at least 7 microns and at most 3 mm in the heat treatment step.
    Since the size of the watch piece is at least about 70 μm and at most about 30 mm, the watch piece is formed of a plurality of crystals (constituting a polycrystal), and a variation of the hardness of the watch piece can be removed.
    In addition, it is preferred that in the shaping step, the watch part is shaped after the heat treatment step and before the etching step.
    When the heat treatment step is performed after the shaping step, a curvature or the like occurs due to heat treatment, and the accuracy of the dimensions of the watch piece is reduced. In addition, when the shaping step is performed after the etching step, the metal luster produced by etching is damaged. Therefore, by performing the shaping step after the heat treatment step and before the etching step, the accuracy of the dimensions of the watch piece is guaranteed, and it is possible to ensure the external appearance.
    In addition, it is preferred to further include an anodizing step in which anodizing is performed on the surface of the watch part after the etching step.
    In this case, a metal luster that shines lustrously with a specific shade can be produced on the surface of the watch piece.
    In addition, an embodiment of the step of immersion etching of the polycrystalline material in a solution containing a fluorinated acid, nitric acid and a solution of hydrogen peroxide is preferred.
    In this case, the surfaces of each crystal of the polycrystalline material obtain a mirror finish, and the directions normal to the surfaces of each crystal may be different from each other.
    In addition, it is preferred that the watch part is an oscillating weight, a main plate, a gear, a balance wheel, a dial or an index such as a needle.
    In this case, a shiny metallic luster may be produced on the surface of each watch piece while removing the hardness variations of each watch piece.
    On the other hand, according to the present invention, in a watch piece made of a polycrystalline material, surfaces of a plurality of crystals included in the polycrystalline material have a mirror finish and the directions normal to the surfaces are different between they.
    According to the invention, in the case where the metal luster is insufficient due to the fact that the action of magnifying the crystals is limited for the removal of a variation of the hardness of the watch piece, the surfaces of each crystal get a mirror finish, and the directions normal to the surfaces of the crystals are different from each other. As a result, a shiny metallic luster may be produced on the surface of the watch piece.
    It is preferred that the grain diameter of the crystals is at least 7 microns and at most 3 mm.
    Since the size of the watch piece is about 70 μm or more and 30 mm or less, the watch piece is formed of a plurality of crystals (constituting a polycrystal), and a variation of the Hardness of the watch piece can be removed.
    In addition, it is preferred that the polycrystalline material is titanium, a titanium alloy or tungsten.
    In addition, anodization may have been performed on the surfaces.
    In this case, a metal luster that shines lustrously with a specific shade can be produced on the surface of the watch piece.
    According to the manufacturing method of the present invention, the metal luster is produced on the surface of the watch part by making the crystals grow in the heat treatment step. Moreover, in the case where the metallic luster is insufficient due to the fact that the action of making the crystals grow is limited for the suppression of the variation of the hardness of the watch piece, the surfaces of each crystal obtain a finish in the etching step, and the directions normal to the surfaces of the crystals are different from each other. Therefore, a shiny metallic luster may be produced on the watch piece surface.
    According to the watch part of the invention, in a case where the metallic luster is insufficient due to the fact that the action of magnifying the crystals is limited for the removal of a variation in hardness of the piece of shows, the surfaces of each crystal receive / obtain a mirror finish, and the directions normal to the surfaces of the crystals are different from each other. As a result, a shiny metallic luster may be produced on the surface of the watch piece.
    Brief description of the drawings
    [0027]<tb> Fig. 1 <SEP> is a plan view of the back side of a watch suit;<tb> fig. 2 <SEP> is a plan view of a front side of a watch movement;<tb> fig. 3 <SEP> is an exploded perspective view of the front side of the watch movement;<tb> fig. 4 <SEP> is the appearance of a base material after heat treatment; and<tb> figs. 5A and 5B <SEP> are cross-sectional views along a line A-A of FIG. 4, fig. 5A having a state before etching, and FIG. 5B having a state after the etching.
    Detailed Description of Preferred Embodiments
    [0028] Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.
    (Watch)
    In general, a mechanical body enclosing a driving portion of a watch is referred to as a "watch movement". A state in which a dial or an index is mounted on the watch movement and inserted into a watch case is referred to as a "complete watch". In both sides of a main plate which constitutes a substrate / a support of the watch, one side of which an ice of the watch case is arranged, that is to say, one side of which the dial is arranged, is referred to as the "back side" of the watch movement, "ice side" or "dial side". In both sides of the main deck, one side of which a bottom of the watch case is arranged, that is, the opposite side of the dial, is referred to as the "front side" of the watch movement or "side bottom of the box.
    FIG. 1 is a plan view of the rear side of the complete watch. The complete watch 1 comprises a dial 2 which has a scale 3 or similar indicating information with respect to time. In addition, an index (a needle) 4 which includes an hour hand 4a indicating the hours, a minute hand 4b indicating the minutes, and a seconds hand 4c indicating seconds, is provided / are provided.
    FIG. 2 is a plan view of the front side of the movement. In addition, in fig. 2, for a better understanding of the drawings, omitting the illustration of a part of the watch parts that constitute the movement 100. A mechanical watch comprises a main plate 102 which constitutes the substrate / support. A winding stem 110 is rotatably constructed in a winding stem guide hole 102a of the main plate 102. A position of an axial direction of the winding stem 110 is determined by a switch device which includes a zipper 190 , a flip-flop 192, a flip-flop spring 194, and a pull-tab 196.
    In addition, when the winding rod 110 is rotated, a winding pinion 112 is rotated by the rotation of a sliding pinion (not shown). A crown wheel 114 and a ratchet (ratchet wheel) 116 are rotated in sequence by a rotation of the winding pinion 112 and a motor spring (not shown) received in the barrel wheel 120 is raised.
    The barrel wheel 120 is rotatably mounted between the main plate 102 and the barrel bridge 160. A mobile (wheel and pinion) center 124, a third mobile (wheel and pinion) 126, a second mobile (wheel and pinion) 128 and a mobile (wheel and pinion) exhaust 130 are rotatably mounted between the main plate 102 and a gear bridge 162. A fork 142 is rotatably mounted between the main plate 102 and a pallet bridge 164 .
    The barrel wheel 120 is rotated by the restoring force of the mainspring, and the central mobile 124, the third mobile 126 and the second mobile 128 and the mobile 130 are rotated in sequence by the rotation of the barrel wheel 120. The barrel wheel 120, the central mobile 124, the third mobile 126 and the second mobile 128 constitute a gear train (front gear). An exhaust and regulator device for controlling a rotation of the front wheel is constituted by the escape wheel 130, the fork 142 and a balance with a spiral 140. A gear 130a is formed on the outer periphery of the escapement wheel 130. The fork 142 includes a pair of pallets 142a. The balance with spiral 140 includes a balance shaft 140a, a balance wheel 140b and a hairspring 140c.
    The mobile 130 is temporarily stopped in a state where the pallet 142a on one side of the fork 142 is engaged with the gear 130a of the exhaust mobile 130. From this state, when the balance with a hairspring 140 is rotated by an expansion or contraction of the hairspring 140c, a dowel pin fixed to the balance pin 140a pivots the yoke 142 upwards. As a result, the pallet 142a on one side of the fork 142 is released from the escape wheel 130, and the escape wheel 130 moves to a position in which the escape wheel is engaged with the pallet 142a. on the other side of the fork 142. Since the balance with spiral 140 is rotated reciprocally in a constant period, the escapement wheel 130 can be escaped (exhausted) at a constant speed.
    When the central mobile 124 is rotated, the roadway (minutes tube) (not shown) is rotated simultaneously based on the rotation, and the minute hand 4b (see Fig. 1) mounted on the roadway indicates the "minutes". In addition, an hour wheel (not shown) is rotated based on the rotation of the roadway by the rotation of the minute wheel and the hour hand 4a (see Fig. 1) mounted on the hour wheel indicates "hours".
    FIG. 3 is an exploded perspective view of the front side of the movement. In addition, in fig. 3, for a better understanding of the drawing, the illustration of part of the watch parts constituting the movement 100 is omitted. The present embodiment is described with the movement 100 of an automatic winding watch of the type called "magic lever" as an example. In the forward side of the barrel bridge 160, an oscillating point 20, a winding wheel 14, a reduction wheel 16 and a ratchet wheel 18 are rotatably mounted.
    The oscillating weight 20 is formed of titanium or the like. The oscillating mass 20 comprises a body of oscillating mass 22 which is formed substantially in semi-circular plate, and a weight 24 arranged along the outer periphery of the oscillating mass body 22. The oscillating mass body 22 and the weight 24 are integral with each other (formed in one piece), but may be fixed by a fastener after being separately formed. The oscillating mass 20 can be viewed from the outside through a transparent box back side. As a result, a metal luster is produced on the surface of the oscillating mass 20. In addition, anodization is performed on the surface of the oscillating mass 20 and the color is applied, and therefore, the external appearance is guaranteed .
    The winding wheel 14 is rotated by the rotation of the oscillating mass 20. In the rear side of the winding wheel 14, an eccentric pin 14a is installed at a position spaced from the center of rotation of the winding wheel 14 A lug lever 30 is rotatably mounted on the eccentric pin 14a. The tab lever 30 has a ring portion 31 which is inserted from the outside at the eccentric pin 14a, a pair of tabs (pawl and pull tab) 32 which extend from the ring portion 31 A reduction wheel 16 is arranged between a pair of tabs 32, and the tips of a pair of tabs 32 are engaged with the outer periphery of the reduction wheel 16. The ratchet wheel 18 is rotated by the rotation of the reduction wheel 16. The ratchet wheel 18 is connected to the barrel wheel (not shown) on the rear side of the barrel bridge 160.
    When the oscillating weight 20 is rotated by the movement of the watch, the winding wheel 14 is rotated. As a result, the leg lever 30 mounted on the eccentric pin 14a of the winding wheel 14 approaches and moves away from the reduction wheel 16. As the leg lever 30 approaches, the push leg presses the teeth of the reduction wheel 16, and the traction tab slides on the toothing. When the leg lever 30 separates (moves apart), the pull tab pulls the toothing of the reduction wheel 16, and the push tab slides over the toothing. As a result, the reduction wheel 16 is rotated in only one direction. When the reduction wheel 16 is rotated, the ratchet wheel 18 and the barrel wheel 120 are rotated. Therefore, the mainspring received in the barrel wheel 120 is automatically raised.
    (Method of manufacturing the watch piece)
    Then, a method of manufacturing a watch part according to an embodiment of the present invention will be described. The method of manufacturing the watch piece according to the present invention can be applied to a watch piece which is formed of polycrystalline material. In particular, the present embodiment is effective for the manufacture of a small watch piece for which the external appearance is important. For example, the oscillating mass 20 or the main plate 102, the gear bridge 162, each gear wheel, the rocker wheel 140b, the dial 2, the index (pins) 4 described above and the like can be manufactured. Hereinafter, a case where the watch piece is made of titanium or a titanium alloy (hereinafter referred to as "titanium or the like"), which is a polycrystalline material, will be described as the example.
    (Heat treatment step)
    First, a base material (plate material, bar material, or the like) of titanium or the like is prepared. Thereafter, the heat treatment is performed relative to the base material, and the titanium crystals or the like are made larger. As the crystals are made larger, the areas of the reflective surfaces of the crystal surface become wider, and a metallic luster is obtained. The pure titanium crystals are recrystallized at 880 ° C, and the atomic arrangement is prepared and grown around the core. As a result, the temperature state of the heat treatment is given as 900 ° C or higher and 1500 ° C or less. In addition, the exposure time is given as 5 hours or more.
    FIG. 4 is the appearance of a base material after the heat treatment. In the example of FIG. 4, the crystals are made larger to about 1 mm by the heat treatment of 950 ° C x 5 hours.
    Regarding the size of the watch part, the small (the smallest) is about 70 microns (for example a diameter of the axis of pendulum 140a or similar) and the large (the largest ) is about 30 mm (for example the oscillating weight 20, or the main plate 102, the dial 2, or the like). As a result, when the titanium crystals or the like are made larger than the size of the watch piece, it is likely that the watch piece is formed for each crystal (that is, a single crystal). In general, since the hardness of each crystal is different in the polycrystalline material, when the watch piece is formed for each crystal, the hardness of the watch piece varies.
    Thus, in the present embodiment, by making the size of the crystal smaller than the size of the piece, the watch piece is formed of a plurality of crystals (constituting a polycrystal), and the variation of the hardness of the watch piece is removed. It is considered preferable that the size of the crystals contained in the watch piece is approximately 1 tenth of the size of the watch piece. Since the size of the watch piece is about 70 μm or more and 30 mm or less, it is preferred that the size of the titanium crystals or the like is 7 μm or more and 3 mm or less. In the heat treatment step described above, the titanium crystals or the like are made larger so that the size of the crystals is 7 μm or more and 3 mm or less. The crystals can be made even larger as the temperature of the heat treatment is higher or the exposure time is longer. In particular, the crystals can be made larger in an effective manner by increasing the temperature.
    (Shaping step)
    Then, after the heat treatment, the base material is shaped to the shape of the watch piece. The method of treatment may be any one selected from pressing, forging, mechanical processing, or the like. When the heat treatment step is performed after the shaping step, bending occurs due to the heat treatment, and the precision of the dimensions of the watch piece is reduced. In addition, when the shaping step is performed after the etching step described below, the metal luster produced by etching is damaged. Therefore, due to the fact that the shaping step is performed after the heat treatment step and before the etching step, the accuracy of the dimensions of the watch piece is guaranteed, and it is possible to ensure external appearance.
    (Step of engraving)
    In the heat treatment step described above, the crystals are made larger in order to produce the metallic luster. However, since the size of the crystals is limited to suppress the hardness variation, the metallic luster can not be obtained sufficiently. Therefore, then, etching is performed on the surface of the watch piece after the shaping step, and a sufficient metallic luster is produced on the surface of the watch piece.
    Figs. 5A and 5B are cross-sectional views taken along line A-A of FIG. 4, of which FIG. 5A is a state before etching, and FIG. 5B is a state after burning.
    Referring to FIG. 5A, a watch piece 40 contains a plurality of crystals 41 to 43 which are made larger in the heat treatment step, and a surface 40s of the watch piece 40 is treated to be flattened in the step shaping. In the etching step, the watch piece 40 is deposited / immersed in an etching solution, and a wet etching is carried out with respect to the surface 40s of the watch piece 40.
    Etching is performed with pretreatment and post-treatment. In the pretreatment, the watch piece is deposited in an aqueous solution of 0.3 to 7% by weight of fluorinated acid (HF). In the post-treatment, the watch piece is deposited in an aqueous solution of 0.3 to 3% by weight of fluorinated acid (HF), from 0.1 to 10% by weight of nitric acid (HNO 3), and from 5 to 35% by weight of hydrogen peroxide solution (H2O2).
    Referring to FIG. 5B, the surfaces 41s to 43s of crystals 41 to 43 of titanium or the like receive a mirror finish by etching. In addition, since each crystal 41 to 43 has a crystal orientation, the surfaces 41s to 43s become, after etching, a surface inclined with respect to the surface 40s before etching. Since each crystal 41 to 43 is deposited around different nuclei, the crystal orientations are different from each other. Consequently, the etching rates of each crystal 41 to 43 are different from each other, and the angles of inclination of the surfaces 41s to 43s after the etching are different from each other. That is to say, the directions 41 v to 43v normal to the surfaces 41s to 43s after the etching are different from each other. As a result, the incident light on the surface of the watch piece 40 is reflected to different directions on the surfaces 41s-43s of the crystals 41-43. As a result, a shiny metallic luster is produced on the surface. of the watch piece 40.
    In addition, the dimensional error allowed for the watch part 40 is about 50 microns. As a result, the etch time is set such that the difference between the crystal having a maximum degree of etching and the crystal having a minimum degree of etching is 50 μm or less. In addition, since the dimensional error exists before the state before the etching step (after the shaping step), it is preferred that the difference in degree of etching be removed from 10 to 30 μm or less.
    (Anodic oxidation step)
    Then, the anodization is performed on the surface of the watch part, and the corrosion resistance is produced. Concretely, the watch piece 40 is deposited in an electrolytic solution and connected to an anode, and an electric current is applied between the anode and a cathode. As a result, the water is electrolyzed and an oxidic titanium film or the like is formed on the surface of the watch piece 40. Here, by adjusting the applied voltage, the surface of the watch piece 40 can be colored differently. varied. Thus, a metallic luster that shines lustrously with a specific hue is produced on the surface of the watch piece 40.
    As described above, the manufacturing method of the watch piece according to the present embodiment comprises a heat treatment step in which the titanium or the like is thermally treated and a plurality of crystals is made to grow. at 43 of titanium or the like, and an etching step in which the titanium is etched or the like, a mirror finish is produced on the surfaces 41s to 43s of the crystals 41 to 43, and the 41v directions are made to 43v normal to 41s to 43s surfaces crystals 41 to 43 different from each other.
    Since the crystals are made larger by the heat treatment step, a metal luster is produced on the surface of the watch piece. In addition, in the case where the metallic luster is insufficient due to the fact that the action of making the crystals grow is limited to suppress a variation of the hardness of the watch piece, the surfaces of the crystals receive a mirror finish in the etching step, and the directions normal to these surfaces are different from each other. As a result, a shiny metallic luster may be produced on the surface of the watch piece.
    The technical scope of the present invention is not limited to the embodiments described above and includes those in which different alterations are applied to the embodiments described above within this range without s'. away from the essence of the present invention. That is, the specific configuration of material or layer or the like described in the embodiments is only one example and can be appropriately modified.
    For example, although the case where the watch piece is made of titanium or the like is described, the present invention may be applied to a case where the watch piece is made of tungsten.
    权利要求:
    Claims (10)
    [1]
    A watch piece made of a polycrystalline material, wherein surfaces (41s, 42s, 43s) of a plurality of crystals (41, 42, 43) included in said polycrystalline material have a mirror finish and the directions (41v, 42v, 43v) normal to these surfaces (41s, 42s, 43s) are different from each other.
    [2]
    The watch piece according to claim 1, wherein a grain diameter of said crystals (41, 42, 43) is at least 7 μm and at most 3 mm.
    [3]
    The watch part according to claim 1 or 2, wherein said polycrystalline material is titanium, a titanium alloy or tungsten.
    [4]
    4. Watch piece according to one of claims 1 to 3, wherein anodization has been performed on the surfaces.
    [5]
    5. Method of manufacturing a watch piece according to one of the preceding claims, which comprises a shaping step in which the watch piece is shaped, the method of manufacture further comprising:a heat treatment step in which, by applying a heat treatment to said polycrystalline material, a plurality of crystals (41, 42, 43) included in said polycrystalline material are grown, andan etching step in which, by subjecting said polycrystalline material to etching, a mirror finish is produced on the outer surfaces (41s, 42s, 43s) of the crystals (41, 42, 43), and directions are made (41v , 42v, 43v) normal to these surfaces (41s, 42s, 43s) different from each other.
    [6]
    6. Manufacturing method according to claim 5, in the heat treatment step of which:the grain diameter of said crystals (41, 42, 43) is enlarged to at least 7 μm and at most 3 mm.
    [7]
    7. The method of manufacture according to claim 5 or 6, in the shaping step of which the watch piece is shaped after the heat treatment step and before the etching step.
    [8]
    The method of manufacture according to one of claims 5 to 7, further comprising:an anodizing step in which anodizing is performed on the surface of the watch piece after the etching step.
    [9]
    The method of manufacture according to one of claims 5 to 8, further comprising:an embodiment of the step of immersion etching said polycrystalline material in a solution that contains a fluorinated acid, nitric acid and a solution of hydrogen peroxide.
    [10]
    10. Method of manufacture according to one of claims 5 to 9, wherein the watch part is an oscillating weight (20), a main plate (102), a gear, a balance wheel (140b), a dial ( 2) or a pointer such as a needle.
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    同族专利:
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    申请号 | 申请日 | 专利标题
    JP2010281040A|JP5971890B2|2010-12-16|2010-12-16|Timepiece parts manufacturing method and timepiece parts|
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